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每周分享11.20

点击次数:699 发布时间:2015/11/20 10:32:42
 In this paper, the ordered mesoporous carbon nanofiber arrays (MCNAs), Nickel–Boron (Ni–B) amorphous alloys, and amorphous Ni–B/MCNAs composite for supercapacitor material have been successfully fabricated by a combination of templating method and chemical reduction process. The porous structure and large specific surface area (1270 m2 g−1) of MCNAs favor the utilization of the active material Ni–B amorphous alloys and interfacial charge transport, and provide short diffusion paths for ions. X-ray diffraction, small-angle X-ray scattering, inductively coupled plasma. Transmission electron micrographs and selected area electronic diffraction were taken to characterize the structure of the ordered MCNAs, Ni–B amorphous alloy, and amorphous Ni–B/MCNAs. Electrochemical properties are characterized by cyclic voltammetry, galvanostatic charge/discharge measurements, and electrochemical impedance spectroscopy. The results show that the amorphous Ni–B/MCNAs display superior capacitive performance (733 F g−1) over Ni–B amorphous alloys (562 F g−1) at a scan rate of 5 mV s−1 and a good cycling stability after 1000 cycles.

该文章中材料表征采用的是美国麦克仪器ASAP 2460

转自中国粉体网

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